Sooo what is gluten.
Gluten is the linkage/bonds between gluten proteins in wheat flour through a complex process. The proteins are called gliadin and glutenin. They form a network called gluten, connected most importantly by disulfide bonds but also by tyrosine bonds, hydrogen bonds and hydrophobe interactions.
The gluten network are made when water is added to the dough and when the dough is being kneaded (so the proteins come close to eachother) and baked.
Reduction will cleave the disulfide bonds.
The disulfide bonds can be broken if the dough is made acidic, by for example vinegar and lemon or lime juice. So by adding this to a cake batter, the cake will become less elastic and more cake-ish.